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An experiment involves reacting 0.02 moles of silver ions with ions of a group 7 element to form 2.868 g of precipitate - Scottish Highers Chemistry - Question 24 - 2022

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Question 24

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An experiment involves reacting 0.02 moles of silver ions with ions of a group 7 element to form 2.868 g of precipitate. Which of the following is the precipitate? ... show full transcript

Worked Solution & Example Answer:An experiment involves reacting 0.02 moles of silver ions with ions of a group 7 element to form 2.868 g of precipitate - Scottish Highers Chemistry - Question 24 - 2022

Step 1

Determine the molar mass of the precipitate

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Answer

To find which silver halide is the precipitate, we first need to determine the molar mass of the potential precipitates. We will also use the mass of the precipitate (2.868 g) to find the moles formed.

Calculating the moles of the precipitate:

[ \text{Moles} = \frac{\text{mass}}{\text{molar mass}} ]

Since we will estimate the molar masses:

  • Molar mass of Silver(I) chloride (AgCl) = 107.87 (Ag) + 35.45 (Cl) = 143.32 g/mol
  • Molar mass of Silver(I) bromide (AgBr) = 107.87 (Ag) + 79.90 (Br) = 187.77 g/mol
  • Molar mass of Silver(I) iodide (AgI) = 107.87 (Ag) + 126.90 (I) = 234.77 g/mol
  • Molar mass of Silver(I) fluoride (AgF) = 107.87 (Ag) + 19.00 (F) = 126.87 g/mol

Step 2

Calculate the moles of the precipitate formed

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Answer

Using the molar mass of Silver(I) chloride as an example:

[ \text{Moles of AgCl} = \frac{2.868 \text{ g}}{143.32 \text{ g/mol}} \approx 0.0200 \text{ moles} ]

For Silver(I) bromide:

[ \text{Moles of AgBr} = \frac{2.868 \text{ g}}{187.77 \text{ g/mol}} \approx 0.0153 \text{ moles} ]

For Silver(I) iodide:

[ \text{Moles of AgI} = \frac{2.868 \text{ g}}{234.77 \text{ g/mol}} \approx 0.0122 \text{ moles} ]

For Silver(I) fluoride:

[ \text{Moles of AgF} = \frac{2.868 \text{ g}}{126.87 \text{ g/mol}} \approx 0.0226 \text{ moles} ]

Step 3

Identify the correct precipitate based on the moles obtained

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Answer

Given that you started with 0.02 moles of silver ions, Silver(I) chloride is produced in a 1:1 ratio, matching the amount of silver ions available.

Thus, the correct precipitate formed is:

B. Silver(I) chloride

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