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Atoms of different elements have different attractions for bonding electrons. Electronegativity is a measure of the attraction an atom involved in a bond has for the... show full transcript
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Electronegativity plays a crucial role in determining how atoms share or transfer electrons during bond formation. In a covalent bond, the difference in electronegativity between two bonded atoms can indicate the bond's polarity. For example, in a bond between hydrogen and chlorine, chlorine is more electronegative, leading to a polarized bond. This affects the molecule's overall charge distribution and its chemical reactivity.
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The electronegativity of elements influences molecular geometry and structure. For instance, in water (H₂O), the oxygen atom's higher electronegativity than hydrogen causes a bent molecular shape due to the unequal distribution of electron density. Such structural variations contribute to the unique physical properties of substances, such as boiling and melting points.
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The electronegativity differences between atoms in a compound affect its physical and chemical properties. For instance, ionic compounds, formed by elements with high differences in electronegativity, exhibit high melting and boiling points due to the strong electrostatic forces between ions. On the other hand, molecular compounds with similar electronegativities often have lower boiling points and are typically gases or liquids at room temperature. Understanding electronegativity helps predict these properties and the behavior of compounds in chemical reactions.
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