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Ethane-1,2-diol can be made from ethene - Scottish Highers Chemistry - Question 9 - 2018

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Ethane-1,2-diol can be made from ethene. (a) The flow chart of an industrial process to produce ethane-1,2-diol is shown. (i) Industrial processes are designed to ... show full transcript

Worked Solution & Example Answer:Ethane-1,2-diol can be made from ethene - Scottish Highers Chemistry - Question 9 - 2018

Step 1

Using the flowchart, suggest two ways to maximise profit in this industrial process.

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Answer

  1. Recycle (or recover) waste gases to minimize raw material costs.
  2. Use a catalyst to increase the reaction rate, thereby reducing time and costs.

Step 2

Name the process used in Separator 2 to separate ethane-1,2-diol from the larger liquid by-products.

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Answer

Fractional distillation.

Step 3

Explain fully why ethane-1,2-diol is more viscous than propan-1-ol.

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Answer

Ethane-1,2-diol contains two hydroxyl (-OH) groups, which lead to a greater capacity for hydrogen bonding compared to propan-1-ol, which has only one hydroxyl group. The stronger intermolecular forces increase the viscosity of ethane-1,2-diol, making it thicker and harder to flow than propan-1-ol.

Step 4

Draw a structural formula for a diol that contains three carbon atoms.

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Answer

A possible structure is:

  H   H   H
  |    |   |
H-C - C - C - OH
  |    |   |
 OH   OH  H

This represents propane-1,2-diol.

Step 5

Describe the procedure which should be used to prepare 100 cm³ of the 20% ethanol solution.

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Answer

  1. Use a pipette to measure exactly 20 cm³ of ethanol.
  2. Transfer the ethanol into a 100 cm³ volumetric flask.
  3. Add distilled water to the flask until the total volume reaches 100 cm³.
  4. Stopper the flask and invert several times to mix the solution thoroughly.

Step 6

Calculate the total volume, in cm³, of the 20% ethanol solution needed to treat a 3-5 kg animal.

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Answer

For a 3-5 kg animal: Total volume = weight (kg) × 5 cm³ = 3 kg × 5 cm³ = 15 cm³ to 5 kg × 5 cm³ = 25 cm³. Therefore, the total volume required ranges from 15 cm³ to 25 cm³.

Step 7

Draw a structural formula for another possible product of oxidation of ethane-1,2-diol.

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Answer

A possible product is:

  H   O   H
  |    ||  |
H-C - C - C - OH
  |    |    |
 H    H    H

This represents propane-1,2-dione.

Step 8

Give a formula for sodium glycolate.

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Answer

The formula for sodium glycocate is:
NaC₂H₃O₃.

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