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Methyl benzoate is commonly added to perfumes as it has a pleasant smell - Scottish Highers Chemistry - Question 3 - 2018

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Methyl benzoate is commonly added to perfumes as it has a pleasant smell. A student carries out a reaction to produce methyl benzoate using the following apparatus. ... show full transcript

Worked Solution & Example Answer:Methyl benzoate is commonly added to perfumes as it has a pleasant smell - Scottish Highers Chemistry - Question 3 - 2018

Step 1

Describe a safe method of heating a flammable mixture.

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Answer

A safe method to heat a flammable mixture is to use a heating mantle or a hot plate. This prevents the risk of open flames that could ignite the mixture.

Step 2

Suggest a reason why there is a small test tube filled with cold water in the neck of the tube containing the reaction mixture.

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Answer

The small test tube filled with cold water acts as a condenser to prevent the escape of vapors from the reaction mixture. This helps in keeping the reactants contained.

Step 3

Name product X.

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Answer

Product X is water.

Step 4

Explain why benzoic acid is the limiting reactant.

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Answer

To determine the limiting reactant, we first calculate the moles of benzoic acid and methanol used.

The molar mass of benzoic acid (C₇H₆O₂) is 122 g/mol, so:

For 5.0 g of benzoic acid:

extmolesofbenzoicacid=5.0extg122extg/mol=0.041extmoles ext{moles of benzoic acid} = \frac{5.0 ext{ g}}{122 ext{ g/mol}} = 0.041 ext{ moles}

The molar mass of methanol (CH₃OH) is 32 g/mol, so:

For 2.5 g of methanol:

extmolesofmethanol=2.5extg32extg/mol=0.078extmoles ext{moles of methanol} = \frac{2.5 ext{ g}}{32 ext{ g/mol}} = 0.078 ext{ moles}

The balanced equation states that one mole of benzoic acid reacts with one mole of methanol. Therefore, 0.041 moles of benzoic acid would need:

0.041extmolesofCH3OH.0.041 ext{ moles of } CH₃OH.

Since we have 0.078 moles of methanol available, the limiting reactant is benzoic acid.

Step 5

Calculate the cost, in £, of the benzoic acid needed to make 100 g of methyl benzoate using the student’s method.

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Answer

From the experiment, the student produced 3.1 g of methyl benzoate from 5.0 g of benzoic acid. To produce 100 g of methyl benzoate, we can set up a proportion:

5.0extg3.1extg=xextg100extg\frac{5.0 ext{ g}}{3.1 ext{ g}} = \frac{x ext{ g}}{100 ext{ g}}

Thus, solving for x gives:

x=5.0×1003.1161.29extgofbenzoicacidx = \frac{5.0 \times 100}{3.1} \approx 161.29 ext{ g of benzoic acid}

Given that benzoic acid costs £39.80 for 500 g, the cost per gram is:

Cost per gram=39.80500=0.0796ext£/g\text{Cost per gram} = \frac{39.80}{500} = 0.0796 ext{ £/g}

Therefore, the cost for 161.29 g is:

Cost=161.29×0.079612.84ext£\text{Cost} = 161.29 \times 0.0796 \approx 12.84 ext{ £}

Rounding this to the nearest penny gives a final cost of approximately £12.84.

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