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Essential oils from the lavender plant are used in aromatherapy - Scottish Highers Chemistry - Question 10 - 2017

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Essential oils from the lavender plant are used in aromatherapy. (a) Gas chromatography can be used to separate and identify the organic compounds in lavender oils. ... show full transcript

Worked Solution & Example Answer:Essential oils from the lavender plant are used in aromatherapy - Scottish Highers Chemistry - Question 10 - 2017

Step 1

Calculate the relative concentration of linalool in lavender oil A.

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Answer

To find the relative concentration of linalool, we use the formula:

extRelativeconcentration=(Component peak areaTotal peak area)×100 ext{Relative concentration} = \left( \frac{\text{Component peak area}}{\text{Total peak area}} \right) \times 100

Given that the peak area for linalool is 31909 and the total peak area is 79310, we calculate:

Relative concentration of linalool=(3190979310)×10040.23%\text{Relative concentration of linalool} = \left( \frac{31909}{79310} \right) \times 100 \approx 40.23\%

Step 2

Identify the component found in lavender oil A that is missing from lavender oil B.

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Answer

The component found in lavender oil A but missing from lavender oil B is geranyl acetate, noted as peak 5.

Step 3

Calculate the cost, in pence, of 1,8-cineole that is present in a 500 cm³ bottle of this brand of mouthwash.

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Answer

The concentration of 1,8-cineole in the mouthwash is 0.92 mg/cm³. For a 500 cm³ bottle, the total mass is:

Total mass=0.92 mg/cm3×500 cm3=460 mg\text{Total mass} = 0.92 \text{ mg/cm}^3 \times 500 \text{ cm}^3 = 460 \text{ mg}

Convert mass to grams (1000 mg = 1 g):

Total mass in grams=4601000=0.46 g\text{Total mass in grams} = \frac{460}{1000} = 0.46 \text{ g}

The cost for 1 kg (1000 g) of 1,8-cineole is £59.10. The cost for 0.46 g is calculated as follows:

Cost=59.101000×0.46=£0.0271742.72 pence\text{Cost} = \frac{59.10}{1000} \times 0.46 = £0.027174 \approx \text{2.72 pence}

Step 4

Circle the chiral carbon atom in the linalool structure.

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Answer

In the provided structure of linalool, the chiral carbon is the carbon atom attached to the hydroxyl group (OH) and has four different substituents: a methyl group, an ethyl group, two hydrogen atoms, and the hydroxyl group. It should be circled in the diagram accordingly.

Step 5

Write the molecular formula of farnesene.

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Answer

The molecular formula for farnesene, which consists of three isoprene units, is:

C15H24C_{15}H_{24}

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