A student investigated the purity of a sample of magnesium chloride, MgCl₂ - Scottish Highers Chemistry - Question 10 - 2019
Question 10
A student investigated the purity of a sample of magnesium chloride, MgCl₂. The sample was dissolved in water and then an excess of silver nitrate, AgNO₃, was added ... show full transcript
Worked Solution & Example Answer:A student investigated the purity of a sample of magnesium chloride, MgCl₂ - Scottish Highers Chemistry - Question 10 - 2019
Step 1
Explain why the student should use distilled or deionised water, rather than tap water, when preparing the solution.
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Answer
The student should use distilled or deionised water because tap water may contain chloride ions or other impurities, which could react with the silver nitrate and affect the results of the investigation. Distilled or deionised water ensures that these unwanted ions are not present, leading to more accurate results.
Step 2
Complete the table to show the most appropriate piece of apparatus that could be used to measure the required volumes.
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Answer
Measurement
Apparatus
20.0 cm³ (accurately)
Pipette
35 cm³ (approximately)
Measuring cylinder
Step 3
Complete the flow chart below to show the correct order of steps the student should carry out to collect, dry and weigh the precipitate.
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The correct order is:
E → C → B → D → A
This sequence involves first weighing the filter paper, then filtering the precipitate, washing it to remove impurities, drying it in an oven, and finally weighing the precipitate along with the filter paper.
Step 4
Calculate the mass of magnesium chloride, in g, present in the magnesium chloride solution.
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Answer
To find the mass of magnesium chloride, we need to use the molar masses and the stoichiometry of the reaction:
Calculate the moles of silver chloride:
extMolesofAgCl=143.4extg/mol1.393extg=0.0097extmol
From the balanced equation, the molar ratio of MgCl₂ to AgCl is 1:2. Therefore, the moles of MgCl₂ produced are:
Moles of MgCl₂=20.0097=0.00485extmol
Calculate the mass of magnesium chloride:
Mass of MgCl₂=0.00485extmol×95.3extg/mol=0.461extg
Step 5
Calculate the % of magnesium chloride present in the original sample.
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Answer
To calculate the percentage of magnesium chloride in the original impure sample, we use the formula:
Percentage=(mass of impure samplemass of MgCl₂)×100
Substituting in the values:
Percentage=(2.503extg2.403extg)×100=96.0%
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