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Methyl benzoate is commonly added to perfumes as it has a pleasant smell - Scottish Highers Chemistry - Question 3 - 2018

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Methyl benzoate is commonly added to perfumes as it has a pleasant smell. A student carries out a reaction to produce methyl benzoate using the following apparatus. ... show full transcript

Worked Solution & Example Answer:Methyl benzoate is commonly added to perfumes as it has a pleasant smell - Scottish Highers Chemistry - Question 3 - 2018

Step 1

Describe a safe method of heating a flammable mixture.

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Answer

A safe method to heat a flammable mixture is to use a heating mantle or a hot plate. This avoids the risks associated with an open flame, which could ignite the flammable vapors.

Step 2

Suggest a reason why there is a small test tube filled with cold water in the neck of the tube containing the reaction mixture.

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Answer

The small test tube filled with cold water acts as a condenser to prevent the escape of volatile or gaseous reactants, ensuring that they remain in the reaction mixture.

Step 3

Name product X.

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Answer

Product X is water (H₂O).

Step 4

Explain why benzoic acid is the limiting reactant. You must include calculations in your answer.

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Answer

To determine the limiting reactant, we first calculate the number of moles of each reactant:

  • For benzoic acid:

5.0 ext{ g} imes rac{1 ext{ mole}}{122 ext{ g}} = 0.041 ext{ moles}

  • For methanol:

    2.5 ext{ g} imes rac{1 ext{ mole}}{32 ext{ g}} = 0.078 ext{ moles}

From the balanced equation, 1 mole of benzoic acid reacts with 1 mole of methanol. Thus: 1 mole of benzoic acid requires 1 mole of methanol, so: 0.041 moles of benzoic acid would require 0.041 moles of methanol. Since we have 0.078 moles of methanol available, benzoic acid is the limiting reactant.

Step 5

Calculate the cost, in £, of the benzoic acid needed to make 100 g of methyl benzoate using the student’s method.

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Answer

First, we need to determine how much benzoic acid is required to produce 100 g of methyl benzoate.

From the reaction, the molar mass of methyl benzoate (C₈H₈O₂) is 136 g, and the molar mass of benzoic acid (C₇H₆O₂) is 122 g.

Using the ratio:

  • 5 g of benzoic acid produces 3.1 g of methyl benzoate.

  • Thus, to produce 100 g of methyl benzoate:

    ext{Required benzoic acid} = rac{100 ext{ g methyl benzoate} imes 5 ext{ g benzoic acid}}{3.1 ext{ g methyl benzoate}} = 161.3 ext{ g (rounded to 3 significant figures)}.

Next, calculate the cost of 161.3 g of benzoic acid:

  • Cost per gram: rac{39.80 ext{ pounds}}{500 ext{ g}} = 0.0796 ext{ pounds/g}

Total cost: ext{Cost} = 161.3 ext{ g} imes 0.0796 ext{ pounds/g} = 12.81 ext{ pounds}.

Rounding to the nearest penny gives £12.81.

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