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Ethane-1,2-diol can be made from ethene - Scottish Highers Chemistry - Question 9 - 2018

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Question 9

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Ethane-1,2-diol can be made from ethene. (a) The flow chart of an industrial process to produce ethane-1,2-diol is shown. (i) Industrial processes are designed to m... show full transcript

Worked Solution & Example Answer:Ethane-1,2-diol can be made from ethene - Scottish Highers Chemistry - Question 9 - 2018

Step 1

Using the flowchart, suggest two ways to maximise profit in this industrial process.

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Answer

  1. Recycle (waste) gases: Reusing any unreacted ethene or other gases helps in reducing waste and improving cost efficiency.
  2. Use a catalyst: Implementing catalysts can reduce energy requirements and reaction times, leading to lower operational costs.

Step 2

Name the process used in Separator 2 to separate ethane-1,2-diol from the larger liquid by-products.

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Answer

The process used in Separator 2 is fractional distillation.

Step 3

Explain fully why ethane-1,2-diol is more viscous than propan-1-ol.

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Answer

Ethane-1,2-diol has two hydroxyl (-OH) groups, compared to propan-1-ol which has only one. This allows for stronger hydrogen bonding between ethane-1,2-diol molecules, resulting in increased viscosity. The presence of additional -OH groups increases molecular interaction, making it more resistant to flow.

Step 4

Draw a structural formula for a diol that contains three carbon atoms.

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Answer

A possible structural formula for a three carbon diol is:

    HO-CH₂-CH(OH)-CH₃

This shows a compound with two -OH groups attached to the second carbon.

Step 5

Describe the procedure that should be used to prepare 100 cm³ of the 20% ethanol solution.

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Answer

  1. Use a pipette to accurately measure 20 cm³ of ethanol.
  2. Transfer the 20 cm³ of ethanol into a 100 cm³ volumetric flask.
  3. Add distilled water to the flask until the total volume reaches exactly 100 cm³, ensuring proper mixing.

Step 6

Calculate the total volume, in cm³, of the 20% ethanol solution needed to treat a 3-5 kg animal.

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Answer

To calculate the total volume required:

  1. Specify the weight of the animal, using a weight of 4 kg for calculation (the midpoint).

  2. Each kg requires 5 cm³ of solution:

    Total volume = 4 kg × 5 cm³/kg = 20 cm³.

So, the total volume needed to treat a 4 kg animal is 20 cm³.

Step 7

Draw a structural formula for another possible product of oxidation of ethane-1,2-diol.

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Answer

A possible product of the oxidation of ethane-1,2-diol is glycolic acid, which can be represented as:

  HO-CH(OH)-COOH

This shows a carboxylic acid and an -OH group.

Step 8

Give a formula for sodium glycolate.

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Answer

The formula for sodium glycolate is NaC₂H₃O₃.

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