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Which of the following compounds is a tertiary alcohol? A - Scottish Highers Chemistry - Question 5 - 2019

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Which of the following compounds is a tertiary alcohol? A. 2,2-dimethylpropan-1-ol B. 2-methylbutan-2-ol C. pentan-3-ol D. 3-methylbutan-2-ol

Worked Solution & Example Answer:Which of the following compounds is a tertiary alcohol? A - Scottish Highers Chemistry - Question 5 - 2019

Step 1

Identify the structure of each compound

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Answer

To determine which of the given compounds is a tertiary alcohol, we first need to understand what a tertiary alcohol is. A tertiary alcohol is one where the hydroxyl group (-OH) is attached to a carbon that is connected to three other carbon atoms.

  1. 2,2-dimethylpropan-1-ol: The hydroxyl group is on a carbon that is bonded to one carbon (the one on the side chain), hence it is not tertiary.
  2. 2-methylbutan-2-ol: The hydroxyl group is on the second carbon, which is bonded to three other carbon atoms (the two methyl groups and a butyl), making it a tertiary alcohol.
  3. pentan-3-ol: The hydroxyl group is on the third carbon, which is connected to two other carbon atoms (the second and fourth), thus not tertiary.
  4. 3-methylbutan-2-ol: The hydroxyl group here is also connected to a carbon with only two alkyl groups, not qualifying it as tertiary.

Step 2

Evaluate the options for tertiary alcohol

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Answer

After evaluating each compound, we find that B. 2-methylbutan-2-ol is the only compound that qualifies as a tertiary alcohol.

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