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The table shows the first three ionisation energies of aluminium - Scottish Highers Chemistry - Question 4 - 2018

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The table shows the first three ionisation energies of aluminium. Ionisation energy (kJ mol⁻¹) First 578 Second 1817 Third 2745 Using this information,... show full transcript

Worked Solution & Example Answer:The table shows the first three ionisation energies of aluminium - Scottish Highers Chemistry - Question 4 - 2018

Step 1

Al(g) → Al²⁺(g) + 2e⁻ - Calculate the enthalpy change

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Answer

To find the enthalpy change for the reaction where aluminium gas loses two electrons to form Al²⁺, we need to consider the ionization energies provided:

  1. First Ionization Energy: This is the energy required to remove the first electron: 578 kJ mol⁻¹.
  2. Second Ionization Energy: This is the energy required to remove the second electron: 1817 kJ mol⁻¹.

The total enthalpy change for the reaction can be calculated by summing the first and second ionization energies:

extTotalEnthalpyChange=extFirstIE+extSecondIE=578extkJmol1+1817extkJmol1=2395extkJmol1 ext{Total Enthalpy Change} = ext{First IE} + ext{Second IE} = 578 ext{ kJ mol}^{-1} + 1817 ext{ kJ mol}^{-1} = 2395 ext{ kJ mol}^{-1}

Thus, the enthalpy change for the reaction is 2395 kJ mol⁻¹, corresponding to option B.

Step 2

Final selection

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Answer

Therefore, the correct answer is B 2395.

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