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Essential oils from the lavender plant are used in aromatherapy - Scottish Highers Chemistry - Question 10 - 2017

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Essential oils from the lavender plant are used in aromatherapy. (a) Gas chromatography can be used to separate and identify the organic compounds in lavender oils.... show full transcript

Worked Solution & Example Answer:Essential oils from the lavender plant are used in aromatherapy - Scottish Highers Chemistry - Question 10 - 2017

Step 1

Calculate the relative concentration of linalool in lavender oil A.

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Answer

The relative concentration of linalool can be calculated using the formula provided. The peak area for linalool is 31909 and the total peak area is 79310.

The calculation is as follows:

Relative concentration=3190979310×10040.23%\text{Relative concentration} = \frac{31909}{79310} \times 100 \approx 40.23 \%

Thus, the relative concentration of linalool in lavender oil A is approximately 40.23%.

Step 2

Identify the component found in lavender oil A that is missing from lavender oil B.

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Answer

The component found in lavender oil A that is missing from lavender oil B is geranyl acetate (peak 5).

Step 3

Calculate the cost, in pence, of 1,8-cineole that is present in a 500 cm³ bottle.

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Answer

First, we find the total mass of 1,8-cineole in a 500 cm³ bottle:

500cm3×0.92mg/cm3=460mg500\,\text{cm}^3 \times 0.92\,\text{mg/cm}^3 = 460\,\text{mg}

We convert mg to kg:

460mg=0.00046kg460\,\text{mg} = 0.00046\,\text{kg}

Next, we calculate the cost of 460 mg of 1,8-cineole:

Cost of 1 kg of 1,8-cineole = £59.10 = £0.05910 per gram = £0.05910 × 1000 = £59.10 per kg.

Cost of 0.00046 kg:

0.00046kg×£59.10=£0.0271660.00046\,\text{kg} \times £59.10 = £0.027166

Converting to pence (1 pound = 100 pence):

Cost in pence = £0.027166 × 100 ≈ 2.72 pence.

Step 4

Circle the chiral carbon atom in the linalool structure.

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Answer

The chiral carbon atom in the linalool structure is the carbon atom that is connected to four different groups, specifically the carbon atom that is bonded to the –OH group, –CH₃, –H and the remaining carbon chain.

Step 5

Write the molecular formula of farnesene.

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Answer

The molecular formula of farnesene, which consists of three isoprene units, can be represented as (C_{15}H_{24}) or (C_{5}H_{8} ) when considering the connection between isoprene units.

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