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Reacting Masses Simplified Revision Notes

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1.3.2 Reacting Masses

Reacting masses calculations allow us to determine how much of a reactant is needed or how much product will be formed in a chemical reaction. These calculations are based on the mole concept and the stoichiometry of the balanced chemical equation.

Steps for Reacting Masses Calculations

1. Calculate the moles of the given substance

Use the formula:

Moles=MassMr\text{Moles} = \frac{\text{Mass}}{M_r}

Where:

  • Mass is the mass of the substance (in grams).
  • MrM_r is the relative molecular or formula mass.

2. Use the balanced chemical equation

Use this equation to determine the mole ratio between the known and unknown species (reactant and product).

3. Calculate the moles of the unknown species

Multiply the moles of the known species by the mole ratio from the balanced equation.

4. Convert moles of the unknown species to mass

Use the same formula:

Mass=Moles×Mr\text{Mass} = \text{Moles} \times M_r

This gives the mass of the unknown species (either reactant or product).

infoNote

Example: Calculating the Mass of Oxygen Required to React with Hydrogen Question: What mass of oxygen gas (O₂) is needed to react with hydrogen gas (H₂) to produce 9 g of water (H₂O)?


Step 1: Write the balanced chemical equation:

2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O

Step 2: Calculate moles of water: The molar mass of water (H₂O) is 18 g/mol.

Moles of H2O=9g18g/mol=0.5mol\text{Moles of H}_2O = \frac{9 \, \text{g}}{18 \, \text{g/mol}} = 0.5 \, \text{mol}

Step 3: Use the mole ratio: From the balanced equation, 2 moles of H₂O are produced by 1 mole of O₂.

Therefore, for 0.5 moles of water, the required moles of oxygen are:

Moles of O2=0.52=0.25mol\text{Moles of O}_2 = \frac{0.5}{2} = 0.25 \, \text{mol}

Step 4: Convert moles of O₂ to mass: The molar mass of oxygen gas (O₂) is 32 g/mol.

Mass of O2=0.25×32g/mol=8g\text{Mass of O}_2 = 0.25 \times 32 \, \text{g/mol} = 8 \, \text{g}

Therefore, 8 g of oxygen is required.

infoNote

Example: Mass of a Reactant or Product: Question: How much calcium carbonate (CaCO₃) is required to produce 44 g of carbon dioxide (CO₂) in the reaction:

CaCO3CaO+CO2CaCO_3 \rightarrow CaO + CO_2

Solution:

  • MrM_r of CO₂ = 44 g/mol
  • So moles of CO₂ = 44 g / 44 g/mol = 1 mol.
  • From the balanced equation, 1 mol of CaCO₃ produces 1 mol of CO₂
  • So moles of CaCO₃ = 1 mol.
  • MrM_r of CaCO₃ = 100 g/mol
  • So the mass of CaCO₃ required = 1 mol × 100 g/mol = 100 g.
infoNote

Example: Mass of a Compound in Solution: Question: How much sodium hydroxide (NaOH) is needed to completely react with 50 cm³ of 1 mol/dm³ hydrochloric acid (HCl) in the reaction:

NaOH+HClNaCl+H2ONaOH + HCl \rightarrow NaCl + H_2O

Solution:

  • Moles of HCl = 1 mol/dm³ × (50 cm³ / 1000 cm³/dm³) = 0.05 mol.
  • From the balanced equation, 1 mole of NaOH reacts with 1 mole of HCl.
  • So, moles of NaOH = 0.05 mol.
  • MrM_r of NaOH = 40 g/mol.
  • Therefore, mass of NaOH = 0.05 mol × 40 g/mol = 2 g.
infoNote

Summary

Reacting masses calculations are essential for determining the quantities of reactants or products in a chemical reaction. The steps involve converting mass to moles, using the balanced chemical equation to find the mole ratio, and then calculating the mass or volume of the unknown species. Mastering these calculations is crucial for solving many types of chemistry problems.

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