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Half Equations & Ionic Equations Simplified Revision Notes

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1.1.4 Half Equations & Ionic Equations

Half Equations

infoNote

Half equations are used to represent the oxidation or reduction processes in a redox reaction. They show how electrons are transferred during these reactions.

In a half equation:

  • Oxidation is the loss of electrons.
  • Reduction is the gain of electrons. Example of Oxidation:

When sodium (Na) loses an electron to form a sodium ion (Na⁺): NaNa++e\text{Na} \rightarrow \text{Na}^+ + e^-

Example of Reduction:

When chlorine (Cl₂) gains electrons to form chloride ions (Cl⁻): Cl2+2e2Cl\text{Cl}_2 + 2e^- \rightarrow 2\text{Cl}^-

Balancing Half Equations:

  • It is important to ensure that the number of electrons lost in the oxidation half equation equals the number of electrons gained in the reduction half equation.
  • This allows for the correct combination of half equations to form a full ionic equation.

Ionic Equations

infoNote

Ionic equations show only the species that are directly involved in the chemical reaction. Spectator ions, which do not change during the reaction, are omitted.

infoNote

Steps to Write an Ionic Equation:

  1. Write the balanced chemical equation for the reaction.
  2. Separate the aqueous compounds into their respective ions.
  3. Identify and remove the spectator ions (ions that appear unchanged on both sides of the equation).
  4. Write the remaining ions that are involved in the reaction, forming the ionic equation.
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Example:

  • Consider the reaction between silver nitrate (AgNO₃) and sodium chloride (NaCl) in aqueous solution: AgNO3(aq)+NaCl(aq)AgCl(s)+NaNO3(aq)\text{AgNO}_3 (aq) + \text{NaCl} (aq) \rightarrow \text{AgCl} (s) + \text{NaNO}_3 (aq)
  • In ionic form: Ag+(aq)+NO3(aq)+Na+(aq)+Cl(aq)AgCl(s)+Na+(aq)+NO3(aq)\text{Ag}^+ (aq) + \text{NO}_3^- (aq) + \text{Na}^+ (aq) + \text{Cl}^- (aq) \rightarrow \text{AgCl} (s) + \text{Na}^+ (aq) + \text{NO}_3^- (aq)
  • The spectator ions (Na⁺ and NO₃⁻) are removed, leaving the ionic equation: Ag+(aq)+Cl(aq)AgCl(s)\text{Ag}^+ (aq) + \text{Cl}^- (aq) \rightarrow \text{AgCl} (s)
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