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3.2.4 Limiting Reactants

What is a Limiting Reactant?

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In a chemical reaction, the limiting reactant is the substance that gets used up first, limiting the amount of product that can be formed. Once this reactant is gone, the reaction stops, even if other reactants are still available.

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Worked Example:

  • Let's say 7.95 g of copper oxide (CuO)(CuO) reacts with 7.2 g of carbon (C)(C) to produce copper (Cu)(Cu) and carbon dioxide (CO2(COâ‚‚):
  1. Calculate the moles:
  • Moles of CuO:
7.95g79.5(MrofCuO)=0.1moles\frac{7.95 g}{79.5 (Mr of CuO)} = 0.1 moles
  • Moles of C:
7.2g12(ArofC)=0.6moles\frac{7.2 g}{12 (Ar of C)}= 0.6 moles
  1. Determine the limiting reactant:
  • The balanced equation shows CuOCuO and C C react in a 2:1 ratio. To react with 0.1 moles of CuOCuO, you only need 0.05 moles of carbon. Since we have much more carbon, CuO is the limiting reactant.
  1. Calculate the mass of products:
  • Using the mole ratio from the balanced equation, 0.1 moles of CuOCuO will produce 0.1 moles of CuCu and 0.05 moles of CO2COâ‚‚.
  • Mass of Cu:
0.1Ă—63.5=6.35g0.1Ă—63.5=6.35 g
  • Mass of COâ‚‚:
0.05Ă—44=2.2g0.05Ă—44=2.2 g
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