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The pH Scale & Neutralisation Simplified Revision Notes

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4.2.6 The pH Scale & Neutralisation

What are Acids and Bases?

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Acids and bases can be defined based on the ions they produce when dissolved in water:

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Acids: Substances that produce hydrogen ions (H⁺) in aqueous solutions. The more H⁺ ions a substance produces, the more acidic it is. Bases: Substances that produce hydroxide ions (OH⁻) in aqueous solutions. Bases that are soluble in water are called alkalis. When an alkali dissolves in water, it creates an alkaline solution. The more OH⁻ ions a substance produces, the more basic (or alkaline) it is.

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Common Examples of Acids and Bases

  • Acidic Substances: Examples include vinegar, citric acid, and milk (although milk is only very mildly acidic).
  • Basic (Alkaline) Substances: Bases are often found in cleaning products. Common examples include bleach and ammonia, both of which are strongly basic compounds.
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Understanding the nature of acids and bases is fundamental to grasping the pH scale, as it is the concentration of H⁺ and OH⁻ ions that determines the pH and whether a substance is acidic, neutral, or alkaline.

The pH Scale

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The pH Scale is a widely used method for measuring the acidity or alkalinity (basicity) of a substance. The scale indicates the concentration of hydrogen ions (H⁺) in a solution, with pH being a logarithmic measure of this concentration. The lower the pH value, the higher the concentration of H⁺ ions, making the solution more acidic.

  • pH Range: The pH scale ranges from 0 to 14, with 7 being neutral.
    • Acidic Substances: Have a pH between 0 and 6. The closer the pH is to 0, the stronger the acid. Examples include:
    • Battery acid (pH 0)
    • Vinegar (pH 3)
    • Milk (pH 6)
    • Neutral Substances: Have a pH of 7. Pure water is a common example.
    • Alkaline (Basic) Substances: Have a pH between 8 and 14. The closer the pH is to 14, the stronger the base. Examples include:
    • Baking soda (pH 9)
    • Ammonia (pH 11)
    • Blood (pH 8)

Measuring pH

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pH can be measured using a universal indicator, which is a chemical mixture that changes colour depending on the pH of the solution. When added to an acid or base, the indicator produces a colour that corresponds to a specific pH value on the pH scale. For example:

  • Red typically indicates a strong acid (pH 1-3).
  • Green indicates a neutral solution (pH 7).
  • Purple indicates a strong alkali (pH 12-14).

Neutralisation Reactions

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Neutralisation is a chemical reaction between an acid and a base that results in the formation of a salt and water.

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The general word equation for this type of reaction is: Acid+BaseSalt+WaterAcid+Base→Salt+Water

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In a neutralisation reaction:

  • The H⁺ ions from the acid react with the OH⁻ ions from the base to form water (H₂O).
  • The remaining ions from the acid and base combine to form a salt.

Formation of Salts

Salts are ionic compounds that result from the neutralisation of an acid by a base. They are typically formed when the cations (positive ions) from the base combine with the anions (negative ions) from the acid.

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For example:

  • When hydrochloric acid (HCl) reacts with sodium hydroxide (NaOH), sodium chloride (NaCl) and water (H₂O) are formed: HCl+NaOHNaCl+H2OHCl+NaOH→NaCl+H₂O
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Salts are often insoluble in water, meaning they do not dissolve easily and may form a precipitate. A precipitate is a solid that forms in solution and settles at the bottom of the reaction vessel. This can be separated from the solution using filtration.

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In summary, the pH Scale provides a measure of how acidic or alkaline a substance is, while neutralisation is the process of mixing an acid and a base to form a neutral solution, typically resulting in the formation of a salt and water. Understanding these concepts is fundamental to many chemical processes and reactions.

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