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Amount of Substance in Relation to Volumes of Gases Simplified Revision Notes

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3.5.1 Amount of Substance in Relation to Volumes of Gases

Understanding Molar Gas Volume

infoNote

At room temperature (20°C) and standard pressure (1 atm), one mole of any gas occupies a volume of 24 dm³ (or 24,000 cm³). This is known as the molar gas volume. This relationship is useful because if you know the number of moles of a gas, you can easily calculate its volume, and vice versa.

Using the Molar Gas Volume to Calculate Volume

infoNote

To find the volume of a gas in dm³, use the formula:

Volume(dm3)=Moles×24Volume (dm^3)=Moles×24
  • If you need the volume in cm³, multiply the volume in dm³ by 1,000.
infoNote

Worked Example 1

  • Problem: Calculate the volume of 7.52 g of ammonia (NH3)(NH₃) gas at room temperature and pressure.
  1. Calculate moles of NH₃:
MrofNH3=14(N)+3×1(H)=17 Mr of NH_3=14 (N)+3×1 (H)=17MolesofNH3=7.52g17=0.44molMoles of NH3= \frac{7.52 g}{17}=0.44 mol
  1. Calculate volume:
Volume=0.44×24=10.56dm3 Volume=0.44×24=10.56 dm^3
infoNote

Worked Example 2

  • Problem: 3.25 g of zinc (Zn) reacts with excess hydrochloric acid (HCl)(HCl) to form zinc chloride (ZnCl2)(ZnCl₂) and hydrogen gas (H2)(H₂). Calculate the volume of hydrogen gas produced.
  1. Calculate moles of zinc:
MolesofZn=3.25g65(MrofZn)=0.05mol Moles of Zn= \frac{3.25 g}{65 (Mr of Zn)}=0.05 mol
  1. Use mole ratio from the balanced equation: Since the ratio of ZnZn to H2H₂ is 1:1, the moles of hydrogen gas produced will also be 0.05 mol.
  2. Calculate the volume of hydrogen gas:
Volume=0.05×24=1.2dm3 Volume=0.05×24=1.2 dm^3
  1. Convert to cm³:
1.2×1000=1200cm3 1.2×1000=1200 cm^3
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