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Drawing the Structural Formula of a Carboxylic Acid Simplified Revision Notes

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Drawing structural formula

Drawing structural formula

  • If you were asked to draw the full structural formula of a carboxylic acid, such as 2-methyl butanoic acid, follow these steps:

Identify the Type of Compound:

  • Recognise that it is a carboxylic acid (alkanoic acid) from the '-oic' ending in the name.

Determine the Carbon Chain Length:

  • Identify the number of carbon atoms in the chain. In this example, 'butan' indicates a four-carbon chain.

Locate Substituents:

  • Identify any branches or substituents. For example, '2-methyl' indicates a methyl branch on the second carbon atom.

Draw the Carbon Chain:

  • Draw a line representing the carbon chain with the correct number of carbon atoms. Ensure there are bonds between each carbon atom.

Attach the Carboxyl Group:

  • On one end of the chain, attach the -COOH group. This group includes the carboxyl functional group (-COOH) and represents the acidic part of the molecule.

Attach Substituents:

  • Find the specified carbon atom for the substituent (e.g., the second carbon in '2-methyl') and attach the indicated group (-CH₃ in this case) to that carbon atom.

Diagram showing structural formula construction

Complete the Structure:

  • Fill in the remaining bonds on each carbon atom with hydrogen atoms (H) to complete the structure.

Drawing structural formula

diagram

Example:

  • For 2-methylbutanoic acid, you would draw a four-carbon chain, with a carboxyl group (-COOH) attached to one end and a methyl group (-CH₃) attached to the second carbon atom. Hydrogen atoms would fill the remaining bonds.

Conclusion:

  • Drawing the structural formula of a carboxylic acid involves recognising the compound type, determining the carbon chain length, locating substituents, and systematically attaching the functional groups and substituents to the carbon chain. This process ensures an accurate representation of the molecule's structure.
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