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Oxidation of Alcohols-The OH Ratio. Simplified Revision Notes

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Oxidation of Alcohols-The O
Ratio

Oxidation of Alcohols-The O
Ratio

Diagram

The O
Ratio:

  • When we talk about the oxidation of organic compounds, we are referring to changes in the ratio of oxygen (O) atoms to hydrogen (H) atoms within the molecule.
  • This ratio can change in two ways: increasing the O
    ratio
    or decreasing it, depending on whether we are oxidising or reducing the compound.
  • Let's explore these concepts in more detail.

Increasing the O
Ratio (Oxidation):

  • When we oxidise an organic compound, we increase the O
    ratio
    . This can be achieved by either adding oxygen (O) atoms to the molecule or removing hydrogen (H) atoms from it.
  • One common example of oxidation is combustion, where an organic compound is burned completely. For instance, when we burn alcohol, such as ethanol (Câ‚‚Hâ‚…OH), it reacts with oxygen (Oâ‚‚) to produce carbon dioxide (COâ‚‚) and water (Hâ‚‚O):
  • Equation: Câ‚‚Hâ‚…OH + 3Oâ‚‚ → 2COâ‚‚ + 3Hâ‚‚O
  • This process increases the O
    ratio because we are adding oxygen atoms and forming more oxygen-containing compounds (COâ‚‚ and Hâ‚‚O).

Decreasing the O
Ratio (Reduction):

  • Conversely, when we reduce an organic compound, we decrease the O
    ratio
    . This can be achieved by either removing oxygen atoms or adding hydrogen atoms to the molecule.
  • Partial oxidation of organic compounds can lead to the production of different organic compounds with lower O
    ratios.

Oxidation of Alcohols-The O
Ratio

Chemistry

Conclusion:

  • Understanding the O
    ratio
    is essential in organic chemistry, as it helps us describe how the composition of organic molecules changes during oxidation and reduction reactions.
  • Oxidation increases the O
    ratio
    by adding oxygen or removing hydrogen, while reduction decreases the O
    ratio
    by removing oxygen or adding hydrogen.
  • Complete oxidation, such as combustion, results in the formation of carbon dioxide and water, with a significant increase in the O
    ratio
    . Partial oxidation can lead to various organic products with varying O
    ratios.
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