An indigestion tablet contains a mass of 0.30 g of magnesium hydroxide [Mg(OH)₂] as its only basic ingredient - Leaving Cert Chemistry - Question 10 - 2005
Question 10
An indigestion tablet contains a mass of 0.30 g of magnesium hydroxide [Mg(OH)₂] as its only basic ingredient. The balanced chemical equation for the reaction betwee... show full transcript
Worked Solution & Example Answer:An indigestion tablet contains a mass of 0.30 g of magnesium hydroxide [Mg(OH)₂] as its only basic ingredient - Leaving Cert Chemistry - Question 10 - 2005
Step 1
Calculate the volume of 1.0 M HCl neutralised by two of these indigestion tablets.
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Answer
To find the volume of HCl neutralised, we first need to calculate the number of moles of magnesium hydroxide in two tablets:
The mass of one tablet is 0.30 g.
For two tablets:
Mass=2×0.30g=0.60g
Calculate moles of Mg(OH)₂:
Molar mass of Mg(OH)₂ = 24.31 + 2(16.00) + 2(1.01) = 58.33 g/mol
Moles of Mg(OH)₂ = 58.330.60=0.0103mol
From the balanced equation, 1 mole of Mg(OH)₂ reacts with 2 moles of HCl. Therefore:
Moles of HCl required = 2×0.0103=0.0206mol
Using the concentration of HCl (1.0 M):
Volume of HCl = 1.00.0206=0.0206L=20.6cm3
Rounded to the nearest cm³, the answer is 21 cm³.
Step 2
What mass of salt is formed in this neutralisation?
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Answer
The salt formed is magnesium chloride (MgCl₂). To find the mass:
Moles of Mg(OH)₂ = 0.0103 mol (from previous calculation).
Each mole of Mg(OH)₂ produces 1 mole of MgCl₂:
Thus, moles of MgCl₂ = 0.0103 mol.
Molar mass of MgCl₂ = 24.31 + 2(35.45) = 95.21 g/mol.
Mass of MgCl₂ = moles × molar mass:
Mass = 0.0103×95.21=0.980≈0.98g.
Step 3
How many magnesium ions are present in this amount of the salt?
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Answer
Since each formula unit of MgCl₂ contains one magnesium ion, the number of magnesium ions can be calculated:
Moles of MgCl₂ = 0.0103 mol (from previous part).
Number of ions = moles × Avogadro's number (approximately 6.022×1023 ions/mol).
Total magnesium ions = 0.0103mol×6.022×1023ions/mol=6.20×1021Mg2+extions.
Step 4
What volume of this second indigestion remedy would have the same neutralising effect on stomach acid as two of the indigestion tablets mentioned earlier?
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Answer
To find the volume of the second remedy that has a 6% (w/v) concentration, we need the amount of Mg(OH)₂ required:
We know from earlier that 0.60 g of Mg(OH)₂ is needed.
A 6% (w/v) solution means 6 g of solute in 100 cm³ of solution.
Therefore, in 1 cm³, the amount of Mg(OH)₂ is:
100cm36g=0.06g/cm3.
To find the required volume (V) that provides 0.60 g:
V=0.06g/cm30.60g=10cm3.
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