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An indigestion tablet contains a mass of 0.30 g of magnesium hydroxide [Mg(OH)₂] as its only basic ingredient - Leaving Cert Chemistry - Question 10 - 2005

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An indigestion tablet contains a mass of 0.30 g of magnesium hydroxide [Mg(OH)₂] as its only basic ingredient. The balanced chemical equation for the reaction betwee... show full transcript

Worked Solution & Example Answer:An indigestion tablet contains a mass of 0.30 g of magnesium hydroxide [Mg(OH)₂] as its only basic ingredient - Leaving Cert Chemistry - Question 10 - 2005

Step 1

Calculate the volume of 1.0 M HCl neutralised by two of these indigestion tablets.

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Answer

To find the volume of HCl neutralised, we first need to calculate the number of moles of magnesium hydroxide in two tablets:

  1. The mass of one tablet is 0.30 g.

  2. For two tablets: Mass=2×0.30g=0.60g\text{Mass} = 2 \times 0.30 \, \text{g} = 0.60 \, \text{g}

  3. Calculate moles of Mg(OH)₂:

    • Molar mass of Mg(OH)₂ = 24.31 + 2(16.00) + 2(1.01) = 58.33 g/mol
    • Moles of Mg(OH)₂ = 0.6058.33=0.0103mol\frac{0.60}{58.33} = 0.0103 \, \text{mol}
  4. From the balanced equation, 1 mole of Mg(OH)₂ reacts with 2 moles of HCl. Therefore:

    • Moles of HCl required = 2×0.0103=0.0206mol2 \times 0.0103 = 0.0206 \, \text{mol}
  5. Using the concentration of HCl (1.0 M):

    • Volume of HCl = 0.02061.0=0.0206L=20.6cm3\frac{0.0206}{1.0} = 0.0206 \, \text{L} = 20.6 \, \text{cm}^3
    • Rounded to the nearest cm³, the answer is 21 cm³.

Step 2

What mass of salt is formed in this neutralisation?

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Answer

The salt formed is magnesium chloride (MgCl₂). To find the mass:

  1. Moles of Mg(OH)₂ = 0.0103 mol (from previous calculation).

  2. Each mole of Mg(OH)₂ produces 1 mole of MgCl₂:

    • Thus, moles of MgCl₂ = 0.0103 mol.
  3. Molar mass of MgCl₂ = 24.31 + 2(35.45) = 95.21 g/mol.

  4. Mass of MgCl₂ = moles × molar mass:

    • Mass = 0.0103×95.21=0.9800.98g0.0103 \times 95.21 = 0.980 \approx 0.98 \, \text{g}.

Step 3

How many magnesium ions are present in this amount of the salt?

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Answer

Since each formula unit of MgCl₂ contains one magnesium ion, the number of magnesium ions can be calculated:

  1. Moles of MgCl₂ = 0.0103 mol (from previous part).

    • Number of ions = moles × Avogadro's number (approximately 6.022×1023 ions/mol6.022 \times 10^{23} \text{ ions/mol}).
  2. Total magnesium ions = 0.0103mol×6.022×1023ions/mol=6.20×1021Mg2+extions0.0103 \, \text{mol} \times 6.022 \times 10^{23} \, \text{ions/mol} = 6.20 \times 10^{21} \, \text{Mg}^{2+} ext{ ions}.

Step 4

What volume of this second indigestion remedy would have the same neutralising effect on stomach acid as two of the indigestion tablets mentioned earlier?

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Answer

To find the volume of the second remedy that has a 6% (w/v) concentration, we need the amount of Mg(OH)₂ required:

  1. We know from earlier that 0.60 g of Mg(OH)₂ is needed.

    • A 6% (w/v) solution means 6 g of solute in 100 cm³ of solution.
  2. Therefore, in 1 cm³, the amount of Mg(OH)₂ is:

    • 6g100cm3=0.06g/cm3\frac{6 \, \text{g}}{100 \, \text{cm}^3} = 0.06 \, \text{g/cm}^3.
  3. To find the required volume (V) that provides 0.60 g:

    • V=0.60g0.06g/cm3=10cm3V = \frac{0.60 \, \text{g}}{0.06 \, \text{g/cm}^3} = 10 \, \text{cm}^3.

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