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The three pieces of equipment, A, B and C, shown are used in volumetric analysis - Leaving Cert Chemistry - Question 2 - 2012

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The three pieces of equipment, A, B and C, shown are used in volumetric analysis. (a) Name the pieces of equipment A and B. (b) Why is it advisable to use C when m... show full transcript

Worked Solution & Example Answer:The three pieces of equipment, A, B and C, shown are used in volumetric analysis - Leaving Cert Chemistry - Question 2 - 2012

Step 1

Name the pieces of equipment A and B.

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Answer

A is a pipette, and B is a burette. The pipette is used for measuring fixed volumes of liquid accurately, while the burette allows for the delivery of variable amounts of liquid.

Step 2

Why is it advisable to use C when measuring a solution with A?

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Answer

Using C (the burette) is advisable because it allows for precise measurement of the solution being titrated, ensuring that the correct amount is delivered for accurate results.

Step 3

Describe the procedure for rinsing A and B before they are used to measure the solutions used in a titration.

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Answer

Rinse A (the pipette) and B (the burette) by filling each with distilled (or deionized) water and letting it drain. Next, rinse A with a little of the solution that will be measured, making sure to coat the inside of the pipette before filling it to the mark. Rinse B with a small volume of the titrant solution (NaOH) it will contain, ensuring it is ready for accurate titration.

Step 4

Explain why this is so.

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Answer

The last drop of solution must not be blown or shaken out because the pipette is designed to deliver the exact volume it measures, including the last drop. Blowing out this drop would result in delivering less than the required volume, leading to inaccuracies in measurements and affecting the results of the titration.

Step 5

Name one other piece of equipment used in carrying out the titrations.

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Answer

One other piece of equipment used in carrying out titrations is a conical flask.

Step 6

Name a suitable indicator for this titration and state the colour change at the end point.

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Answer

A suitable indicator for this titration is phenolphthalein, which changes from colourless in an acidic solution to pink in a basic solution.

Step 7

Calculate the concentration of the sodium hydroxide solution in moles per litre.

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Answer

The moles of HCl used can be calculated using the concentration and volume:

0.08extM×20.0cm31000=0.0016moles HCl0.08 \, ext{M} \times \frac{20.0 \, \text{cm}^3}{1000} = 0.0016 \, \text{moles HCl}.

Since the stoichiometry of the reaction is 1:1, moles of NaOH = moles of HCl = 0.0016 moles.

The concentration of NaOH can be calculated as follows:

Concentration (C)=molesvolume (L)=0.0016 moles0.025 L=0.064 M\text{Concentration (C)} = \frac{\text{moles}}{\text{volume (L)}} = \frac{0.0016 \text{ moles}}{0.025 \text{ L}} = 0.064 \text{ M}.

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