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A student prepared ethene and ethyne gases and compared their properties - Leaving Cert Chemistry - Question 2 - 2017

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A student prepared ethene and ethyne gases and compared their properties. (a) (i) What was observed in the reaction flask as the water was dropped onto the calcium... show full transcript

Worked Solution & Example Answer:A student prepared ethene and ethyne gases and compared their properties - Leaving Cert Chemistry - Question 2 - 2017

Step 1

What was observed in the reaction flask as the water was dropped onto the calcium carbide (CaC₂)?

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Answer

When water is added to calcium carbide in the reaction flask, the mixture turns cloudy and produces bubbles or effervescence. This is due to the formation of calcium hydroxide and ethyne gas.

Step 2

Explain why the first few test-tubes of gas collected were discarded.

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Answer

The first few test-tubes of gas were discarded because they likely contained moisture and impurities from the reaction. Freshly produced ethyne gas is the desired product, free from water vapor or byproducts.

Step 3

Draw a labelled diagram of a suitable arrangement of apparatus and chemicals for the preparation and collection of ethene.

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Answer

The diagram should include a reaction flask with ethene being collected over water. The setup includes ethanoic acid as a reactant, a delivery tube, and a water bath. Ensure to label each component accurately.

Step 4

State and explain two safety precautions that should be taken when carrying out the experiment.

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Answer

  1. Use protective eyewear to prevent eye injury from splashes or reactions.
  2. Work in a well-ventilated area to avoid inhalation of any gases produced during the reaction.

Step 5

Combustion tests were carried out on samples of ethene and ethyne. Compare the observations made in the two tests.

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Answer

During the combustion test, ethene burns with a blue flame, producing less soot and showing a clean burning. Ethyne, on the other hand, burns with a luminous yellow flame, indicating the production of more soot due to incomplete combustion.

Step 6

Write a balanced equation for the complete combustion of ethene in oxygen.

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Answer

The balanced equation for the complete combustion of ethene (C₂H₄) is:

C2H4+3O22CO2+2H2OC_2H_4 + 3O_2 → 2CO_2 + 2H_2O

Step 7

Name a reagent used to test the gases for unsaturation.

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Answer

A common reagent used to test for unsaturation in gases is bromine water (Br₂ in water), which changes color when it reacts with unsaturated hydrocarbons.

Step 8

Calculate the maximum theoretical number of ethyne molecules produced in this reaction.

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Answer

Given that 0.05 moles of calcium carbide (CaC₂) was used and considering the molar ratio from the equation, the maximum number of ethyne (C₂H₂) molecules produced can be calculated as follows:

  1. Determine moles of CaC₂: 0.05 moles
  2. From the reaction, 1 mole of CaC₂ produces 1 mole of C₂H₂.
  3. Thus, moles of C₂H₂ produced = 0.05 moles.
  4. To find the number of molecules, use Avogadro's number (6.022 x 10²³):

0.05extmolesimes6.022imes1023extmolecules/mole=3.01imes1022extmolecules0.05 ext{ moles} imes 6.022 imes 10^{23} ext{ molecules/mole} = 3.01 imes 10^{22} ext{ molecules}

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