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A student investigated the rate of decomposition of a hydrogen peroxide (H₂O₂) solution using manganese dioxide (MnO₂) as a catalyst - Leaving Cert Chemistry - Question 3 - 2018

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A student investigated the rate of decomposition of a hydrogen peroxide (H₂O₂) solution using manganese dioxide (MnO₂) as a catalyst. The equation for the reaction i... show full transcript

Worked Solution & Example Answer:A student investigated the rate of decomposition of a hydrogen peroxide (H₂O₂) solution using manganese dioxide (MnO₂) as a catalyst - Leaving Cert Chemistry - Question 3 - 2018

Step 1

Name a suitable piece of apparatus to measure out 5 cm³ of hydrogen peroxide solution A.

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Answer

A suitable piece of apparatus to measure 5 cm³ of hydrogen peroxide solution is a graduated pipette or a graduated syringe. These apparatus allow for accurate measurement of liquid volumes.

Step 2

Describe the appearance of the MnO₂ catalyst.

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Answer

The manganese dioxide (MnO₂) catalyst appears as a black solid or powder. It is generally dark in color and may have a granular texture when viewed under normal laboratory conditions.

Step 3

Copy into your answerbook the diagram of the arrangement of apparatus shown in the box below.

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Answer

To complete the diagram, you should include:

(i) The location of the catalyst just before the reaction is started by labeling it as 'catalyst' inside the flask labeled A. (ii) Show the arrangement of flexible tubing leading from the flask to a gas syringe labeled Y, which is used to collect the oxygen gas evolved during the reaction. Make sure to indicate that the gas syringe is inverted over water to measure the volume of gas accurately.

Step 4

Plot a graph (on graph paper) of volume of O₂ (y-axis) versus time (x-axis).

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Answer

The graph should show the volume of oxygen (in cm³) on the y-axis against time (in minutes) on the x-axis. Each data point from the provided table should be accurately plotted. The axes must be labeled with their respective units. The plotted points should then be connected smoothly, forming a curve that gradually flattens as time progresses.

Step 5

Why does the rate of this reaction slow down as the reaction proceeds?

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Answer

The rate of reaction slows down because as the hydrogen peroxide is consumed, its concentration decreases. According to the principle of reaction rates, a lower concentration of reactants results in fewer collisions between reactant molecules, leading to a slower formation of products, in this case, oxygen gas.

Step 6

Use your graph to find the volume of oxygen produced in the first 2.5 minutes.

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Answer

By locating the 2.5-minute mark on the x-axis, you can trace upwards to the graph curve to find the corresponding volume of oxygen produced. This should give you a precise value as indicated by the curve.

Step 7

On the same sheet of graph paper sketch the curve you would expect to get if you repeated the experiment, instead using 2.5 cm³ of hydrogen peroxide solution A diluted to 25 cm³.

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Answer

You should sketch a new curve on the same graph that starts at the origin and rises but is less steep than the original curve, indicating that a smaller volume of hydrogen peroxide would produce oxygen more slowly. Ensure to label this new line appropriately.

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