A group of students prepared ethano l (C2H5OH) by slowly adding a mixture of ethanol (C2H5OH) and an oxidising agent in water, to hot aqueous sulphuric acid - Leaving Cert Chemistry - Question 1 - 2005
Question 1
A group of students prepared ethano l (C2H5OH) by slowly adding a mixture of ethanol (C2H5OH) and an oxidising agent in water, to hot aqueous sulphuric acid. The app... show full transcript
Worked Solution & Example Answer:A group of students prepared ethano l (C2H5OH) by slowly adding a mixture of ethanol (C2H5OH) and an oxidising agent in water, to hot aqueous sulphuric acid - Leaving Cert Chemistry - Question 1 - 2005
Step 1
Identify this solid and state its purpose.
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Answer
The solid material is identified as pumice stones or porcelain pieces. Its purpose is to prevent bumping during the reaction.
Step 2
Identify a suitable oxidising agent for this preparation.
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A suitable oxidising agent for this preparation is sodium dichromate or potassium permanganate.
Step 3
What is the colour of the mixture in the dropping funnel at the start?
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The colour of the mixture in the dropping funnel at the start is yellow, matching the oxidising agent used.
Step 4
What is the colour of the mixture in the reaction flask as the reaction proceeds?
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The colour of the mixture in the reaction flask changes to green as the reaction proceeds, due to the reduction of the permanganate.
Step 5
Why is it important to distill off the ethanol as it is produced?
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It is important to distill off the ethanol as it is produced to prevent excessive oxidation and avoid the production of ethanoic acid.
Step 6
Why is it not necessary to keep heating the reaction flask during the addition?
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It is not necessary to keep heating the reaction flask during the addition because the reaction is exothermic, generating sufficient heat.
Step 7
Why is the receiving vessel cooled in ice-water?
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The receiving vessel is cooled in ice-water to condense the ethanol vapor effectively and to maintain a lower temperature.
Step 8
What colour is the solid produced when a mixture containing a few drops of Fehling’s solutions (No 1 and No 2) and ethanol is heated?
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The solid produced is brick red, indicating the presence of copper(I) oxide.
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