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State Avogadro's law - Leaving Cert Chemistry - Question a - 2009

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State Avogadro's law. Give two assumptions of the kinetic theory of gases. Give two reasons why real gases deviate from ideal gas behaviour. How many moles of gas... show full transcript

Worked Solution & Example Answer:State Avogadro's law - Leaving Cert Chemistry - Question a - 2009

Step 1

State Avogadro's law.

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Answer

Avogadro's law states that equal (same) volumes of gases, at the same temperature and pressure, contain equal (same) numbers of molecules (particles, moles).

Step 2

Give two assumptions of the kinetic theory of gases.

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Answer

  1. Gases are made up of particles (molecules, atoms) in rapid, random, straight-line motion.
  2. The volume of the particles (molecules, atoms) is negligible compared to the volume of the container.

Step 3

Give two reasons why real gases deviate from ideal gas behaviour.

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  1. Real gases have intermolecular forces that attract or repel particles, whereas ideal gas assumptions neglect these forces.
  2. Real gas particles occupy space which affects the volume available for movement, contrary to the assumption of point particles in ideal gases.

Step 4

How many moles of gas are present in a sample containing 1.8 x 10^24 atoms of chlorine at s.t.p.?

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Answer

To calculate the number of moles, use the formula:

n=NNAn = \frac{N}{N_A}

where:

  • nn is the number of moles,
  • NN is the number of atoms (1.8 x 10^24),
  • NAN_A is Avogadro's number, approximately 6.022x10236.022 x 10^{23} molecules/mole.

Substituting the values:

n=1.8x10246.022x10233.00 molesn = \frac{1.8 x 10^{24}}{6.022 x 10^{23}} \approx 3.00 \text{ moles}

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