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Give two reasons why real gases deviate from ideal behaviour at high pressures and low temperatures. - Leaving Cert Chemistry - Question d - 2018

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Give two reasons why real gases deviate from ideal behaviour at high pressures and low temperatures.

Worked Solution & Example Answer:Give two reasons why real gases deviate from ideal behaviour at high pressures and low temperatures. - Leaving Cert Chemistry - Question d - 2018

Step 1

Molecules (particles) not point masses

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Answer

Real gases consist of molecules that have a finite size, which means they cannot be considered merely as point masses. This finite volume becomes significant at high pressures, where the gas molecules are forced closer together, resulting in non-ideal behavior.

Step 2

Molecules (particles) have non-negligible volume

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Answer

At high pressures, the volume occupied by gas molecules cannot be ignored. As the pressure increases, the actual space available for each molecule decreases, leading to deviations from the ideal gas law.

Step 3

Molecules (particles) attract/repel one another

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Answer

Real gases exhibit intermolecular forces (such as van der Waals forces) that lead to attractions or repulsions between molecules. At low temperatures, these forces become more pronounced, causing deviations from ideal behavior, as the gas molecules are not just colliding elastically.

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