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B (i) Account for the inert nature of nitrogen gas - Leaving Cert Chemistry - Question B - 2005

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B (i) Account for the inert nature of nitrogen gas. (ii) What is meant by nitrogen fixation? (iii) The concentration of NO₂ in the atmosphere has increased in the ... show full transcript

Worked Solution & Example Answer:B (i) Account for the inert nature of nitrogen gas - Leaving Cert Chemistry - Question B - 2005

Step 1

Account for the inert nature of nitrogen gas.

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Answer

Nitrogen gas (N₂) is considered inert due to its high bond energy, which makes it difficult to break. The N≡N triple bond is extremely strong, requiring a significant amount of energy to dissociate. Additionally, nitrogen is a non-polar molecule, meaning it does not easily react with other substances because it lacks partial charges that would attract charged species.

Step 2

What is meant by nitrogen fixation?

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Answer

Nitrogen fixation refers to the conversion of atmospheric nitrogen (N₂) into nitrogen compounds that can be utilized by organisms. This process is essential for synthesizing useful compounds such as ammonia, which are chemically reactive and can be taken up by plants.

Step 3

The concentration of NO₂ in the atmosphere has increased in the past fifty years. Describe with the aid of chemical equations how an increase in the number of cars has contributed to this change.

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Answer

The rise in the number of cars has led to increased emissions of nitrogen oxides (NOₓ), primarily due to combustion processes. The following equations demonstrate this:

  1. The combustion of nitrogen in air can be represented as:
    N2+O22NON_2 + O_2 \rightarrow 2NO
    This reaction occurs under high temperatures, such as those found in car engines, and contributes to the formation of nitrogen monoxide (NO).

  2. The nitrogen monoxide can further react with oxygen to produce nitrogen dioxide:
    2NO+O22NO22NO + O_2 \rightarrow 2NO_2

These reactions illustrate how the increase in vehicular traffic leads to a rise in NO₂ concentrations in the atmosphere.

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