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A (i) What is meant by the term addition polymerisation? (7) (ii) Name the Du Pont chemist pictured on the right who discovered poly(tetrafluoroethene), PTFE - Leaving Cert Chemistry - Question A - 2005

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A--(i)-What-is-meant-by-the-term-addition-polymerisation?-(7)--(ii)-Name-the-Du-Pont-chemist-pictured-on-the-right-who-discovered-poly(tetrafluoroethene),-PTFE-Leaving Cert Chemistry-Question A-2005.png

A (i) What is meant by the term addition polymerisation? (7) (ii) Name the Du Pont chemist pictured on the right who discovered poly(tetrafluoroethene), PTFE. (3) ... show full transcript

Worked Solution & Example Answer:A (i) What is meant by the term addition polymerisation? (7) (ii) Name the Du Pont chemist pictured on the right who discovered poly(tetrafluoroethene), PTFE - Leaving Cert Chemistry - Question A - 2005

Step 1

What is meant by the term addition polymerisation?

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Answer

Addition polymerisation is a chemical reaction in which monomers, which are small molecules, combine to form a large molecule known as a polymer. In this process, the double bonds of the monomers are broken, allowing them to link together to form a long-chain polymer. This results in the formation of a macromolecule with repeating structural units derived from the initial monomers.

Step 2

Name the Du Pont chemist pictured on the right who discovered poly(tetrafluoroethene), PTFE.

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Answer

The chemist is Roy Plunkett.

Step 3

Describe using an equation how poly(tetrafluoroethene) is produced from its monomers.

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Answer

The polymerisation of tetrafluoroethylene (CF₂=CF₂) can be represented by the following equation:

extnCF2ext=CF2ightarrowext(CF2extCF2ext)n ext{nCF}_2 ext{=CF}_2 ightarrow ext{-(CF}_2 ext{-CF}_2 ext{)}_n-

In this reaction, the double bond between the carbon atoms in the monomer (CF₂=CF₂) breaks, allowing the monomers to link together, forming the long-chain polymer poly(tetrafluoroethylene).

Step 4

Give two common uses of PTFE.

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Answer

Two common uses of PTFE include:

  1. Medical body parts, such as blood vessels, joints, and tracheas.
  2. Non-stick coatings for cookware, providing stain resistance on various surfaces and easy cleaning.

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