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The diagram shows a Downs cell used to electrolyse molten sodium chloride - Leaving Cert Chemistry - Question B - 2016

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The diagram shows a Downs cell used to electrolyse molten sodium chloride. (i) Give one everyday application for each product of this electrolysis. (ii) Why must t... show full transcript

Worked Solution & Example Answer:The diagram shows a Downs cell used to electrolyse molten sodium chloride - Leaving Cert Chemistry - Question B - 2016

Step 1

Give one everyday application for each product of this electrolysis.

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Answer

The products of the electrolysis of molten sodium chloride are sodium (Na) and chlorine (Cl₂).

  1. Sodium (Na): Used in street lighting and as a desiccant in various chemical processes.
  2. Chlorine (Cl₂): Commonly used in water treatment to disinfect and kill microorganisms.

Step 2

Why must the electrolyte be molten?

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Answer

The electrolyte, molten sodium chloride, must be molten because it conducts electricity only in this state. In solid form, sodium chloride cannot conduct electricity due to the rigid ionic structure that prevents the movement of ions.

Step 3

What is the function of the steel mesh?

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Answer

The steel mesh serves to prevent the recombination of the products (sodium and chlorine) by keeping them separate during the electrolysis process. This ensures that each product is collected efficiently without mixing.

Step 4

Write a balanced equation for the cell reaction.

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Answer

The balanced equation for the cell reaction in the Downs cell is:

ightarrow ext{Na (l)} + ext{Cl}_2 (g)$$

Step 5

Why is electrolysis the method of choice for the extraction of aluminium from its ores?

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Answer

Electrolysis is preferred for extracting aluminium due to its position in the electrochemical series, where it is more reactive and does not reduce easily. Other chemical reducing agents are not capable of reducing aluminium oxide efficiently, making electrolysis the most effective method.

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