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Strongly electropositive metals, e.g - Leaving Cert Chemistry - Question B - 2021

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Strongly electropositive metals, e.g. aluminium and sodium, are extracted from their ores by electrolysis. Chemical methods can be used to extract other metals, e.g.... show full transcript

Worked Solution & Example Answer:Strongly electropositive metals, e.g - Leaving Cert Chemistry - Question B - 2021

Step 1

Explain the underlined term.

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Answer

Electrolysis is a process that uses electricity to break down a chemical (substance) to cause a chemical reaction.

Step 2

Why must the aluminium oxide be molten?

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Answer

In molten form, ions are free to move, which is essential for conduction during electrolysis.

Step 3

Write balanced equations for the reactions that occur at the graphite electrodes, and for the overall reaction, during the electrolysis of aluminium oxide.

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Answer

At the anode:

ightarrow ext{O}_2 + 4 ext{e}^-$$ At the cathode: $$ ext{Al}^{3+} + 3 ext{e}^- ightarrow ext{Al}$$ Overall reaction: $$ ext{2Al}_2 ext{O}_3 ightarrow 4 ext{Al} + 3 ext{O}_2$$

Step 4

Identify the chemical method used to extract iron from iron ore.

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Answer

Reduction is used, typically involving carbon monoxide, with a reaction in a blast furnace.

Step 5

Suggest a reason why strongly electropositive metals were not isolated before 1800.

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Answer

Before 1800, there was no electricity or the necessary techniques to isolate these highly reactive metals because they were too difficult to reduce.

Step 6

Refer to the electrochemical series to explain why only some metals are found free in nature.

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Answer

Metals lower down in the electrochemical series are more difficult to oxidise, making them less reactive. Those at the bottom are generally found as free metals.

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