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Before battery-powered lamps became available in the early 1900s, carbide lamps that made use of a chemical reaction to produce a flammable hydrocarbon gas that burned with a bright, sooty flame were commonly used on bicycles and motor cars - Leaving Cert Chemistry - Question 1 - 2021

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Question 1

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Before battery-powered lamps became available in the early 1900s, carbide lamps that made use of a chemical reaction to produce a flammable hydrocarbon gas that burn... show full transcript

Worked Solution & Example Answer:Before battery-powered lamps became available in the early 1900s, carbide lamps that made use of a chemical reaction to produce a flammable hydrocarbon gas that burned with a bright, sooty flame were commonly used on bicycles and motor cars - Leaving Cert Chemistry - Question 1 - 2021

Step 1

Identify (i) liquid A

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Answer

Liquid A is water, which is often used in reactions with calcium carbide.

Step 2

Identify (ii) gas B

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Answer

Gas B is acetylene, a flammable hydrocarbon gas produced from calcium carbide.

Step 3

Describe what happens in the reaction flash liquid A is added slowly to calcium carbide.

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Answer

When liquid A (water) is added to calcium carbide, a vigorous reaction occurs, producing acetylene gas and calcium hydroxide. The reaction can be represented by the equation:

CaC2+2H2OC2H2+Ca(OH)2CaC_2 + 2H_2O \rightarrow C_2H_2 + Ca(OH)_2

This reaction generates heat and bubbles of gas.

Step 4

What does the method of collection of B tell you about its solubility in water?

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Answer

The method of collection indicates that gas B (acetylene) is not very soluble in water, as it is collected over water rather than dissolved in it.

Additionally, the first few test-tubes of gas produced may contain impurities or water vapor, and thus, are not used in tests.

Step 5

Gas B is unsaturated. Explain the underlined term.

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Answer

The term 'unsaturated' refers to a compound that contains at least one double or triple bond between carbon atoms. Acetylene, which has a triple bond between the carbon atoms in its molecular structure, is classified as an unsaturated hydrocarbon.

Step 6

Describe how you could carry out a test for unsaturation on a sample of B.

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Answer

To test for unsaturation, you can perform a bromine water test. Add a few drops of bromine water to a sample of gas B (acetylene). If the solution changes from brown or reddish-brown to colorless, it indicates the presence of unsaturation due to the addition reaction of bromine across the double or triple bonds in the hydrocarbons.

Step 7

Give two characteristics of the flame when B is burned in pure oxygen.

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Answer

When acetylene burns in pure oxygen, the flame is very hot and nearly colorless. It produces a bright, luminous flame suitable for welding and gives off less soot compared to burning in air.

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