Before battery-powered lamps became available in the early 1900s, carbide lamps that made use of a chemical reaction to produce a flammable hydrocarbon gas that burned with a bright, sooty flame were commonly used on bicycles and motor cars - Leaving Cert Chemistry - Question 1 - 2021
Question 1
Before battery-powered lamps became available in the early 1900s, carbide lamps that made use of a chemical reaction to produce a flammable hydrocarbon gas that burn... show full transcript
Worked Solution & Example Answer:Before battery-powered lamps became available in the early 1900s, carbide lamps that made use of a chemical reaction to produce a flammable hydrocarbon gas that burned with a bright, sooty flame were commonly used on bicycles and motor cars - Leaving Cert Chemistry - Question 1 - 2021
Step 1
Identify
(i) liquid A
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Answer
Liquid A is water, which is often used in reactions with calcium carbide.
Step 2
Identify
(ii) gas B
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Answer
Gas B is acetylene, a flammable hydrocarbon gas produced from calcium carbide.
Step 3
Describe what happens in the reaction flash liquid A is added slowly to calcium carbide.
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When liquid A (water) is added to calcium carbide, a vigorous reaction occurs, producing acetylene gas and calcium hydroxide. The reaction can be represented by the equation:
CaC2+2H2O→C2H2+Ca(OH)2
This reaction generates heat and bubbles of gas.
Step 4
What does the method of collection of B tell you about its solubility in water?
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The method of collection indicates that gas B (acetylene) is not very soluble in water, as it is collected over water rather than dissolved in it.
Additionally, the first few test-tubes of gas produced may contain impurities or water vapor, and thus, are not used in tests.
Step 5
Gas B is unsaturated.
Explain the underlined term.
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Answer
The term 'unsaturated' refers to a compound that contains at least one double or triple bond between carbon atoms. Acetylene, which has a triple bond between the carbon atoms in its molecular structure, is classified as an unsaturated hydrocarbon.
Step 6
Describe how you could carry out a test for unsaturation on a sample of B.
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To test for unsaturation, you can perform a bromine water test. Add a few drops of bromine water to a sample of gas B (acetylene). If the solution changes from brown or reddish-brown to colorless, it indicates the presence of unsaturation due to the addition reaction of bromine across the double or triple bonds in the hydrocarbons.
Step 7
Give two characteristics of the flame when B is burned in pure oxygen.
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Answer
When acetylene burns in pure oxygen, the flame is very hot and nearly colorless. It produces a bright, luminous flame suitable for welding and gives off less soot compared to burning in air.
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