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Study the reaction scheme below in which compound Y is produced by the reaction of compound X with water - Leaving Cert Chemistry - Question 8 - 2021

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Study the reaction scheme below in which compound Y is produced by the reaction of compound X with water. Y is often called isopropyl alcohol and it is a component i... show full transcript

Worked Solution & Example Answer:Study the reaction scheme below in which compound Y is produced by the reaction of compound X with water - Leaving Cert Chemistry - Question 8 - 2021

Step 1

What is the systematic IUPAC name for Y?

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Answer

The systematic IUPAC name for Y is propane-2-ol or 2-propanol. This name indicates the structure contains a three-carbon chain with the hydroxyl group (-OH) attached to the second carbon.

Step 2

Classify Y as a primary or a secondary alcohol. Justify your answer.

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Answer

Y is classified as a secondary alcohol because the carbon atom bonded to the hydroxyl (-OH) group is attached to two other carbon atoms, making it secondary.

Step 3

Identify Z.

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Answer

Z is propan-2-one, commonly known as acetone.

Step 4

Draw an expanded molecular structure for Y, indicating clearly which of its bonds are formed when Z is reduced.

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Answer

The expanded molecular structure for Y (propane-2-ol) can be represented as follows:

   H   H   H
   |   |   |
H--C--C--C--OH
   |   |   |
   H   H   H

In this structure, the -OH bond is created when Z is reduced, with the carbon atom in Z forming two new bonds with hydrogen and the hydroxyl group.

Step 5

How does the geometry around the carbon atoms in Z change during this reduction reaction?

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The geometry around the carbon atoms in Z changes from trigonal planar to tetrahedral during the reduction reaction. The sp² hybridization in Z converts to sp³ hybridization as new bonds are formed with hydrogen and the hydroxyl group.

Step 6

What type of reaction is involved in the conversion of X to Y?

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Answer

The type of reaction involved in the conversion of X to Y is an addition reaction, specifically hydration.

Step 7

Identify another product of the reaction of X with water.

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Answer

Another product of the reaction of X with water is propanol.

Step 8

Write a balanced equation for the reaction of Y with sodium.

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The balanced equation for the reaction of Y (propane-2-ol) with sodium is:

ightarrow 2 ext{C}_3 ext{H}_7 ext{Na} + ext{H}_2 $$

Step 9

What information does this reaction give about the -OH functional group?

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This reaction indicates that the -OH functional group is an alcohol group that can react with metals like sodium, suggesting its reactivity and confirming that it is a characteristic feature of alcohols.

Step 10

What is the concentration in terms of moles per liter of isopropyl alcohol?

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Answer

Given a hand sanitizer labeled 70% (v/v) isopropyl alcohol, we can calculate the molarity as follows:

  1. For 100 cm³ of solution, there are 70 cm³ of isopropyl alcohol.
  2. The molar mass of isopropyl alcohol (C₃H₈O) is about 60.1 g/mol.
  3. Thus, the amount in grams is:

70extcm3imes0.8extg/cm3=56extg70 ext{ cm}^3 imes 0.8 ext{ g/cm}^3 = 56 ext{ g} 4. Therefore, the moles of isopropyl alcohol is:

rac{56 ext{ g}}{60.1 ext{ g/mol}} = 0.93 ext{ moles} 5. Therefore, the concentration is:

rac{0.93 ext{ moles}}{0.1 ext{ L}} = 9.3 ext{ M}

Step 11

What is the most influential type of intermolecular force that occurs in Z?

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Answer

The most influential type of intermolecular force in Z (isopropyl alcohol) is dipole-dipole interactions, along with hydrogen bonding due to the presence of the hydroxyl group (-OH). These interactions significantly contribute to the physical properties of the substance.

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