Study the reaction scheme and answer the questions that follow - Leaving Cert Chemistry - Question 9 - 2010
Question 9
Study the reaction scheme and answer the questions that follow.
C₂H₄OH
X → C₂H₄
W
PVC
C₂H₃Cl
Z → C₂H₆
(a) Name the molecule in the scheme that contains no tet... show full transcript
Worked Solution & Example Answer:Study the reaction scheme and answer the questions that follow - Leaving Cert Chemistry - Question 9 - 2010
Step 1
Name the molecule in the scheme that contains no tetragonal carbon atoms.
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Answer
The molecule in the scheme that contains no tetragonal carbon atoms is ethene (C₂H₄). Ethene consists of a simple carbon chain with the formula C₂H₄, containing only sp² hybridized carbon atoms.
Step 2
Identify (i) an addition reaction, (ii) a substitution reaction, in the scheme above.
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Answer
(i) An addition reaction in the scheme is the reaction of C₂H₄ with X (which is likely a halogen addition).
(ii) A substitution reaction is the conversion of C₂H₃Cl to C₂H₆, where the chlorine atom is substituted with hydrogen.
Step 3
Describe the mechanism of reaction Y.
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The mechanism of reaction Y involves the following steps:
Electrophilic attack: The electrophile (such as a proton) interacts with the double bond of ethene, forming a carbocation intermediate.
Nucleophilic attack: A nucleophile, such as a chloride ion from HCl, attacks the carbocation to form the final product.
Deprotonation: The structure rearranges if necessary, followed by the loss of a proton to regenerate a stable alkane.
Step 4
State the reagents(s) and condition(s) required to bring about (i) conversion V, (ii) conversion Z.
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Answer
(i) Conversion V requires H₂ in the presence of a catalyst such as Pt, Pd, or Ni, and the reaction conditions typically involve heating or using light.
(ii) Conversion Z requires Cl₂ in the presence of UV light or heat.
Step 5
Draw a labelled diagram to show how conversion X could be carried out in the school laboratory.
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A labelled diagram for conversion X would include an apparatus showing a round-bottom flask with ethylene (C₂H₄) being reacted with appropriate reagents. Labels should indicate components such as the condenser, heating mantle, and any necessary safety equipment.
Step 6
Conversion W involves a three-step synthesis. Draw the structures of the two organic intermediates in this synthesis.
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Answer
The two organic intermediates can be illustrated as follows:
The first intermediate: C₂H₄ (ethene) reacts to yield C₂H₃Cl (chloroethane).
The second intermediate: C₂H₃Cl (chloroethane) can react further with an appropriate reagent yielding C₂H₆ (ethane) in the final step.
Each structure should be clearly labeled with its molecular formula.
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