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Define oxidation in terms of change in oxidation number - Leaving Cert Chemistry - Question b - 2006

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Define oxidation in terms of change in oxidation number. What is the oxidation number of (i) chlorine in NaClO and (ii) nitrogen in NO₂? State and explain the oxid... show full transcript

Worked Solution & Example Answer:Define oxidation in terms of change in oxidation number - Leaving Cert Chemistry - Question b - 2006

Step 1

Define oxidation in terms of change in oxidation number

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Answer

Oxidation can be defined as an increase in oxidation number. This generally occurs when an element loses electrons and thus its oxidation state increases.

Step 2

What is the oxidation number of (i) chlorine in NaClO

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Answer

The oxidation number of chlorine in NaClO is +1.

Step 3

What is the oxidation number of (ii) nitrogen in NO₂

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Answer

The oxidation number of nitrogen in NO₂ is +4.

Step 4

State and explain the oxidation number of oxygen in the compound OF₂

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Answer

The oxidation number of oxygen in OF₂ is +2. This is because oxygen is more electropositive in this context compared to fluorine, which is the more electronegative element.

Step 5

Identify the reducing agent

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Answer

In the reaction between acidified potassium manganate(VII) and potassium iodide, the reducing agent is potassium iodide (I⁻).

Step 6

Predict the colour change you would expect to see if you carried out this reaction

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Answer

The initial colour of the potassium manganate(VII) solution is purple. Upon reaction, it changes to yellow due to the formation of Mn²⁺ ions, while the iodine produced imparts a brown/red colour.

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