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A student investigated the rate of the reaction that took place between a solution of HCl and the calcium carbonate (CaCO₃) in broken eggshell - Leaving Cert Chemistry - Question 7 - 2019

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A student investigated the rate of the reaction that took place between a solution of HCl and the calcium carbonate (CaCO₃) in broken eggshell. The reaction that too... show full transcript

Worked Solution & Example Answer:A student investigated the rate of the reaction that took place between a solution of HCl and the calcium carbonate (CaCO₃) in broken eggshell - Leaving Cert Chemistry - Question 7 - 2019

Step 1

(i) Plot a graph on graph paper, or mass (mg) on the y-axis versus time.

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Answer

To correctly plot the graph, start by labeling the x-axis as 'Time (minutes)' and the y-axis as 'Mass of CO₂ produced (mg)'. Scale the axes appropriately where the time ranges from 0 to 8 and the mass from 0 to 120 mg. Plot the data points for each time interval given in the table, joining them with a smooth curve to represent the trend.

Step 2

(ii) Use your graph to find the mass of gas produced in the first 3.5 minutes.

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From the plotted graph, find the point that corresponds to 3.5 minutes on the x-axis. Trace vertically until it intersects with the curve. The y-value at this intersection will provide the mass of CO₂ produced in the first 3.5 minutes. Based on the graph, it can be estimated approximately to be around 90 mg.

Step 3

Does the rate of this reaction increase or decrease with time?

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The rate of the reaction decreases with time. As the reaction proceeds, the concentration of the reactants decreases, resulting in fewer collisions between reactant molecules.

Step 4

Give a reason for your answer.

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As the eggshell (CaCO₃) is consumed and the concentration of HCl decreases, the rate of the reaction slows down, leading to a decrease in the rate of CO₂ production over time.

Step 5

(i) Suggest a method for crushing broken eggshell to a powder.

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Answer

A suitable method for crushing broken eggshells would be to use a mortar and pestle for effective grinding.

Step 6

(ii) Predict and explain the effect on the rate of reaction of reducing the size of the eggshell pieces.

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Reducing the size of the eggshell pieces will likely increase the rate of the reaction. This is because a larger surface area allows for more collisions between reactant molecules, facilitating faster reaction rates. The increased exposure of the solid surface to the acid means more effective contact points for the reaction to occur.

Step 7

State the effect on the rate of reaction of increasing the temperature by 10 °C.

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Answer

Increasing the temperature by 10 °C will increase the rate of reaction. Typically, higher temperatures result in increased kinetic energy among the reactant molecules, leading to more frequent and energetic collisions, thereby accelerating the reaction rate.

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