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The structure of the cinnamaldehyde molecule is shown - Leaving Cert Chemistry - Question g - 2016

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The structure of the cinnamaldehyde molecule is shown. How many moles of cinnamaldehyde are there in 1.65 g of the pure compound? (Structure of cinnamaldehyde) The... show full transcript

Worked Solution & Example Answer:The structure of the cinnamaldehyde molecule is shown - Leaving Cert Chemistry - Question g - 2016

Step 1

How many moles of cinnamaldehyde are there in 1.65 g of the pure compound?

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Answer

To find the number of moles in 1.65 g of cinnamaldehyde:

  1. Calculate the Molar Mass (Mr):

    • C: 12 g/mol
    • H: 1 g/mol
    • O: 16 g/mol
    • Total for C9H8O: Mr=9(12)+8(1)+16=132extg/molMr = 9(12) + 8(1) + 16 = 132 ext{ g/mol}
  2. Calculate the Number of Moles (n):

    • Using the formula: n=massMrn = \frac{mass}{Mr}
    • Substitute the values: n=1.65132=0.0125 molesn = \frac{1.65}{132} = 0.0125 \text{ moles}

Step 2

How would you confirm the presence of the sulfite ion in aqueous solution?

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Answer

To confirm the presence of the sulfite ion (SO₃²⁻) in an aqueous solution, you can carry out the following test:

  1. Add an Acid:

    • Introduce a dilute acid such as hydrochloric acid (HCl) to the solution.
  2. Observe for Gas Evolution:

    • If sulfite ions are present, the addition of acid will liberate sulfur dioxide (SO₂), which can be identified by its characteristic smell and by turning acidified potassium dichromate solution from orange to green due to the reduction of Cr₂O₇²⁻ to Cr³⁺.
  3. Confirmatory Test with Barium Chloride:

    • You may also add barium chloride; if sulfite ions are present, a white precipitate of barium sulfite (BaSO₃) may form when reacted with the acidified solution.

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