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a) What is a base? 6 (b) Define pH - Leaving Cert Chemistry - Question 7 - 2020

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a) What is a base? 6 (b) Define pH. Calculate the pH of a 0.05 M NaOH solution correct to one decimal place. 12 (c) What is hard water? 6 (... show full transcript

Worked Solution & Example Answer:a) What is a base? 6 (b) Define pH - Leaving Cert Chemistry - Question 7 - 2020

Step 1

What is a base?

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Answer

A base is a substance that gives hydroxyl (hydroxide) ions (OH⁻) in aqueous solution (water) or acts as a proton (hydrogen ion, H⁺) acceptor. This means bases can react with acids to form salts and water and typically have a pH value above 7.

Step 2

Define pH.

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Answer

The term pH is defined as:

pH=extlog[H+]pH = - ext{log} [H^+]

or equivalently,

pH=14pOHpH = 14 - pOH

where [H⁺] is the concentration of hydrogen ions in the solution.

Step 3

Calculate the pH of a 0.05 M NaOH solution correct to one decimal place.

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To calculate the pH of a 0.05 M NaOH solution:

  1. Determine the pOH: pOH=extlog(0.05)=1.3pOH = - ext{log}(0.05) = 1.3

  2. Calculate the pH using the relation: pH=14pOH=141.3=12.7pH = 14 - pOH = 14 - 1.3 = 12.7

Thus, the pH is 12.7.

Step 4

What is hard water?

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Hard water is defined as water that lathers poorly with soap and is characterized by the presence of dissolved minerals, specifically calcium (Ca²⁺) and magnesium (Mg²⁺) ions.

Step 5

Is the water at source acidic or basic?

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Answer

The water is basic since the pH at the source is 7.2.

Step 6

How does the label indicate that the water is hard?

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The label indicates that the water is hard by referencing high concentrations of calcium and magnesium ions, which are typically present in hard water.

Step 7

How does the label indicate that the water contains temporary hardness?

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The label indicates the presence of temporary hardness by noting the levels of bicarbonates, such as hydrogen carbonate (243 mg/l), which can precipitate upon boiling.

Step 8

What observation confirms the presence of sulfate ions in the mineral water?

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The addition of barium chloride (BaCl₂) solution to the mineral water would produce a white precipitate (barium sulfate), confirming the presence of sulfate ions.

Step 9

Give an advantage of drinking this water instead of tap-water.

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Answer

One advantage of drinking this mineral water instead of tap water is that it contains essential minerals such as calcium and magnesium, which are beneficial for bone health.

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