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Ionic Bonding Simplified Revision Notes

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Ionic Bonding

What is an Ionic Bond?

An Ionic bond is an electrostatic force of attraction between oppositely charged ions when electrons are transferred from one atom to another.

An ion is formed when atoms (or groups of atoms) have either lost or gained electrons.

  • A positive ion (cation) has lost one or more electrons.
  • A negative ion (anion) has gained one or more electrons.
  • Ions are extremely small, with cations generally being smaller than their parent atoms and anions larger.
infoNote

Example of an ionic bond: Sodium Chloride

  • Sodium belongs to the alkali metals in Group 1.
  • Atoms of elements in this group want to lose one electron to have a stable structure.
  • Chlorine belongs to the halogens in group VII and elements in this group want to gain one electron to have a stable structure.
  • Therefore, in this bond, the sodium atom NaNa donates its single outer electron to chlorine.
  • The NaNa atom then becomes the sodium ion (Na+Na^+), the Cl atom then becomes the chloride ion (ClCl^-).
  • The opposite charges attract each other.
  • This force of attraction holds the ionic bond together as shown in the diagrams below.

Electrostatic Force of Attraction

The electrostatic force of attraction between sodium and chloride ions is not just one-to-one but occurs in all directions around an ion.

  • Therefore an ionic compound such as NaClNaCl consists not just of a pair of ions but a network of ions held together in a three-dimensional regular and repeating pattern.
  • In the case of NaClNaCl, this lattice of ions is a cube as shown in the diagram below

The ionic crystal lattice structure of sodium chloride:

image

Characteristics of Ionic compounds

  1. Conduct electricity when melted or in solution as their ions are free to move

  2. Have high melting and boiling points due to attraction between ions

  3. Most ionic substances dissolve in water

  4. Exist as solids at room temperature

Everyday Use of Ionic Materials

  • Salt Tablets: Used to replace salt lost during sweating.
  • Water Softening: Ionic compounds are used to remove calcium and magnesium ions from hard water.
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